Q 1 :

IUPAC name of following compound (P) is:                  [2024]

  • 1,1-Dimethyl-3-ethylcyclohexane

     

  • 3-Ethyl-1,1-dimethylcyclohexane

     

  • 1-Ethyl-3,3-dimethylcyclohexane

     

  • 1-Ethyl-5,5-dimethylcyclohexane

     

(2)

 



Q 2 :

Cyclohexene  is ______ type of an organic compound.                       [2024]

  • Alicyclic

     

  • Benzenoid aromatic

     

  • Benzenoid non-aromatic

     

  • Acyclic

     

(1)

Cyclic compounds that are not aromatic are called alicyclic.
Cyclohexene is an alicyclic compound.

 



Q 3 :

The molecular formula of second homologue in the homologous series of mono carboxylic acids is ______.               [2024]

  • C3H6O2

     

  • C2H4O2

     

  • CH2O

     

  • C2H2O2

     

(2)

 



Q 4 :

Bond line formula of HOCH(CN)2 is:                           [2024]

  •  

  •  

  •  

  •  

(4)

 



Q 5 :

According to IUPAC system, the compound  is named as                 [2024]

  • Cyclohex-1-en-3-ol

     

  • Cyclohex-2-en-1-ol

     

  • Cyclohex-1-en-2-ol

     

  • 1-Hydroxyhex-2-ene

     

(2)

 



Q 6 :

Structure of 4-Methylpent-2-enal is:                           [2024]

  •  

  •  

  •  

  •  

(4)



Q 7 :

IUPAC name of following compound is:                             [2024]

  • 2-Aminopentanenitrile

     

  • 2-Aminobutanenitrile

     

  • 3-Aminobutanenitrile

     

  • 3-Aminopropanenitrile

     

(3)

The compound is 3-Aminobutanenitrile.

 



Q 8 :

Given below are two statements:                                                            [2024]

Statement I: IUPAC name of

is 7-hydroxyheptan-2-one.

Statement II: 2-oxoheptan-7-ol is the correct IUPAC name for above compound.

In the light of the above statements, choose the most appropriate answer from the options given below:

  • Statement I is correct but Statement II is incorrect.

     

  • Statement I is incorrect but Statement II is correct.

     

  • Both Statement I and Statement II are correct.

     

  • Both Statement I and Statement II are incorrect.

     

(1)

Name of the compound is 7-hydroxyheptan-2-one

 



Q 9 :

Identify structure of 2,3-dibromo-1-phenylpentane.                               [2024]

  •  

  •  

  •  

  •  

(2)

 



Q 10 :

Number of σ and π bonds present in ethylene molecule is respectively:                  [2024]

  • 4 and 1

     

  • 5 and 1

     

  • 5 and 2

     

  • 3 and 1

     

(2)

a bonds = 5

π bonds = 1

 

 



Q 11 :

The correct nomenclature for the following compound is:                          [2024]

  • 2-Carboxy-4-hydroxyhept-6-enal

     

  • 2-formyl-4-hydroxyhept-6-enoic acid

     

  • 2-Carboxy-4-hydroxyhept-7-enal

     

  • 2-formyl-4-hydroxyhept-7-enoic acid

     

(2)

When –CHO is part of parent chain, then prefix for it is oxo and when –CHO is not part of parent chain, then prefix for it is formyl. So name of compound is 2-formyl-4-hydroxyhept-6-enoic acid.

 



Q 12 :

Functional group present in sulphonic acids is:                           [2024]

  •  

  • -SO4H

     

  • -SO2

     

  • -SO3H

     

(4)

Functional group in sulphonic acids is -SO3H.

 



Q 13 :

In the given compound, the number of 2° carbon atom/s is ________.                 [2024]

  • Four

     

  • Three

     

  • One

     

  • Two

     

(3)

Carbon connected to one other carbon is primary (1°) carbon.
Carbon connected to two other carbons is secondary (2°) carbon and carbon connected to three other carbons is tertiary (3°) carbon.

 



Q 14 :

IUPAC name of following hydrocarbon (X) is:                                 [2024]

  • 3,4,7-Trimethyloctane

     

  • 2-Ethyl-2,6-diethylheptane

     

  • 2,5,6-Trimethyloctane

     

  • 2-Ethyl-3,6-dimethylheptane

     

(3)

 



Q 15 :

Given below are two statements:                                  [2024]

In the light of the above statements, choose the most appropriate answer from the options given below: 

  • Statement I is correct but Statement II is incorrect

     

  • Both Statement I and Statement II are incorrect

     

  • Statement I is incorrect but Statement II is correct

     

  • Both Statement I and Statement II are correct

     

(3)

 



Q 16 :

Number of compounds among the following which contain sulphur as heteroatom is ______.                    [2024]
Furan, Thiophene, Pyridine, Pyrrole, Cysteine, Tyrosine



(2)

 



Q 17 :

The total number of ‘Sigma’ and ‘Pi’ bonds in 2-formylhex-4-enoic acid is ______.                [2024]



(22)

 



Q 18 :

The total number of ‘sigma’ and ‘Pi’ bonds in 2-oxohex-4-ynoic acid is ______.             [2024]



(18)

σ Bonds = 14

π Bonds = 4

 Total = 14 + 4 =18



Q 19 :

The IUPAC name of the following compound is:                       [2025]

  • 6-Methoxycarbonyl-2,5-dimethylhexanoic acid.

     

  • 2-Carboxy-5-methoxycarbonylhexane.

     

  • Methyl-6-carboxy-2,5-dimethylhexanoate.

     

  • Methyl-5-carboxy-2-methylhexanoate.

     

(1)

 



Q 20 :

The alkane from below having two secondary hydrogens is:                  [2025]

  • 2,2,4,5-Tetramethylheptane

     

  • 2,2,3,3-Tetramethylpentane

     

  • 4-Ethyl-3,4-dimethyloctane

     

  • 2,2,4,4-Tetramethylhexane

     

(2)

Alkane Structure Number of 2° H
2,2,4,5-Tetramethylheptane 4
2,2,3,3-Tetramethylpentane 2
4-Ethyl-3,4-dimethyloctane 10
2,2,4,4-Tetramethylhexane 4

 



Q 21 :

In the given structure, number of sp and sp² hybridized carbon atoms present respectively are:              [2025]

  • 4 and 5

     

  • 4 and 6

     

  • 3 and 5

     

  • 3 and 6

     

(3)

 



Q 22 :

Match List I with List II.                             [2025]

Choose the correct answer from the options given below:

  • (A-III), (B-II), (C-IV), (D-I)

     

  • (A-III), (B-II), (C-I), (D-IV)

     

  • (A-II), (B-III), (C-IV), (D-I)

     

  • (A-II), (B-III), (C-I), (D-IV)

     

(3)

Based on IUPAC nomenclature rules.

 

 



Q 23 :

Total number of sigma (σ) ____ and pi(π) ____ bonds respectively present in hex-1-en-4-yne are:                [2025]

  • 3 and 13

     

  • 14 and 3

     

  • 11 and 3

     

  • 13 and 3

     

(4)

 



Q 24 :

In 3,3-dimethylhex-1-ene-4-yne, there are ____ sp3, ____ sp2 and ____ sp hybridised carbon atoms respectively:                 [2025]

  • 4, 2, 2

     

  • 3, 3, 2

     

  • 2, 4, 2

     

  • 2, 2, 4

     

(1)

 



Q 25 :

What is the correct IUPAC name of                          [2025]

  • 3-Bromo-2-hydroxy-5-nitrobenzoic acid

     

  • 3-Bromo-4-hydroxy-1-nitrobenzoic acid

     

  • 2-Hydroxy-3-bromo-5-nitrobenzoic acid

     

  • 5-Nitro-3-bromo-2-hydroxybenzoic acid

     

(1)

Numbering is done to give lowest set of locants, starting from principal functional group. Substituents are placed in alphabetical order in IUPAC name.

 



Q 26 :

The IUPAC name of the following compound is:                 [2025]

  • 4-Hydroxyhept-1-en-6-yne

     

  • 4-Hydroxyhept-6-en-1-yne

     

  • Hept-6-en-1-yn-4-ol

     

  • Hept-1-en-6-yn-4-ol

     

(4)

When double bond and triple bond are at equivalent positions, then double bond gets lower locant.

 



Q 27 :

Which of the following is the correct IUPAC name of given organic compound (X)?                  [2025]

  • 2-Bromo-2-methylbut-2-ene

     

  • 3-Bromo-3-methylprop-2-ene

     

  • 1-Bromo-2-methylbut-2-ene

     

  • 4-Bromo-3-methylbut-2-ene

     

(3)

When double bond is at equivalent position from both ends of principal chain, then numbering is done from the end so as to give lowest locant to substituents.

 



Q 28 :

What is the correct IUPAC name of                   [2025]

  • 4-Ethyl-1-hydroxycyclopent-2-ene

     

  • 1-Ethyl-3-hydroxycyclopent-2-ene

     

  • 1-Ethylcyclopent-2-en-3-ol

     

  • 4-Ethylcyclopent-2-en-1-ol

     

(4)

Priority order of giving lowest locants is: functional group > double bond > substituents

 



Q 29 :

The sum of sigma (σ) and pi(π) bonds in Hex-1,3-dien-5-yne is ______.                    [2025]



(15)

 



Q 30 :

The correct IUPAC nomenclature for the following compound is:             [2023]

  • 5-Methyl-2-oxohexan-6-oic acid

     

  • 5-Formyl-2-methylhexanoic acid

     

  • 2-Methyl-5-oxohexanoic acid

     

  • 2-Formyl-5-methylhexan-6-oic acid

     

(3)