Q 1 :

Consider the following reactions

Na2B4O7Δ2X+Y

CuSO4+YNon-luminous flameZ+SO3

2Z+2X+CarbonLuminous flame2Q+Na2B4O7+CO

The oxidation states of Cu in Z and Q, respectively are:  [2026]

  • +2 and +2

     

  • +1 and +1

     

  • +2 and +1

     

  • +1 and +2

     

(3)

Na2B4O7Δ(2NaBO2)(X)+B2O3

CuSO4+B2O3Non-luminous flameΔCu+2(BO2)2(Blue bead)(Z)+SO3

2Cu(BO2)2+2NaBO2+CLuminous flameΔ2Cu+1BO2Colorless(Q)+Na2B4O7+CO



Q 2 :

Which is not correct in case of Be and Al?

  • Both are rendered passive by conc. HNO3

     

  • Both give hydroxides which are basic

     

  • Carbides of both give methane on hydrolysis

     

  • Both give covalent chlorides

     

(2)

Both give hydroxides which are Amphoteric oxides.



Q 3 :

Correct order of IP1 is

  • B>Al>Ga>In>Tl

     

  • B>Tl>Ga>Al>In

     

  • B>Ga>Al>Tl>In

     

  • B>Al>Ga>Tl>In

     

(2)

B>Tl>Ga>Al>In

801 > 589 > 579 > 577 > 558 (kJ/mol)


 

 


Q 4 :

Assertion (A): In water, orthoboric acid behaves as weak monobasic acid.

Reason (R): In water, orthoboric acid acts as proton donor.

  • Assertion (A) is True, Reason (R) is True; Reason (R) is a Correct explanation for Assertion (A)

     

  • Assertion (A) is True, Reason (R) is True; Reason (R) is NOT a Correct explanation for Assertion (A)

     

  • Assertion (A) is True, Reason (R) is False

     

  • Assertion (A) is False, Reason (R) is True

     

(3)

Assertion (A) is True, Reason (R) is False



Q 5 :

Maximum number of atoms present in a plane in diborane is X. Maximum number of atoms present in a plane in Borazine is Y. Then, what is the value of X+Y2 ?

(Consider those planes which contain maximum number of atoms)



(9)

B2H6-6=x

B3N3H6-12=y

x+y2=182=9