Q 1 :

A student added aqueous chlorine to aqueous sodium bromide and the resulting mixture was shaken with an equal volume of trichloroethane.

Which diagram best represents the observation made?

  • [IMAGE 75]

     

  • [IMAGE 76]

     

  • [IMAGE 77]

     

  • [IMAGE 78]

     

(4)

[IMAGE 79]

Cl2+2NaBrBr2+2NaCl

Cl2 oxidises Br- to Br2 in trichloroethane and is reddish brown in colour. Two layers are observed as trichloroethane is immiscible with water.



Q 2 :

Match the Column – I and Column – II

  Column – I   Column – II
A) Hypophosphoric acid P) All hydrogens are ionizable in water
B) Pyrophosphoric acid Q) Lewis acid
C) Boric acid R) Monobasic acid
D) Hypophosphorous acid S) sp3 hybridized central atom

 

  • A-PS; B-PS; C-QR; D-RS

     

  • A-QR; B-PS; C-PQ; D-RS

     

  • A-PS; B-QR; C-RS; D-S

     

  • A-QS; B-PR; C-PQ; D-P

     

(1)

 



Q 3 :

Which one of the following orders is not in accordance with the property stated against it?

  • F>Cl>Br>I : Electronegativity

     

  • F2>Cl2>Br2>I2 : Bond dissociation energy

     

  • F2>Cl2>Br2>I2 : Oxidizing power

     

  • HI>HBr>HCl>HF : Acidic strength

     

(2)

(b) Bond dissociation energy order

Cl2>Br2>F2>I2242.6192.8158.8151.1 kJ/mol