Q.

Given below are two statements :

Statement I : Elements ‘X’ and ‘Y’ are the most and least electronegative elements, respectively among N, As, Sb and P. The nature of the oxides X2O3 and Y2O3 is acidic and amphoteric, respectively.

Statement II : BCl3 is covalent in nature and gets hydrolysed in water. It produces [B(OH)4]- and [B(H2O)6]3+ in aqueous medium.

In the light of the above statements, choose the correct answer from the options given below :      [2026]

1 Both Statement I and Statement II are true  
2 Statement I is false but Statement II is true  
3 Statement I is true but Statement II is false  
4 Both Statement I and Statement II are false  

Ans.

(3)

Electronegativity order : N>P>As>Sb

                                                                                

                               Most electronegative    Least electronegative

X=N       X2O3=N2O3 (Acidic)

Y=Sb    Y2O3=Sb2O3 (Amphoteric)

Statement-I is true

BCl3+3H2OB(OH)3+3HCl

Statement-II is false