Q 1 :    

m-chlorobenzaldehyde on treatment with 50% KOH solution yields                 [2024]

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(2)



Q 2 :    

Given below are two statements:                                                                                             [2024]

Statement I: Acidity of α-hydrogens of aldehydes and ketones is responsible for Aldol reaction.

Statement II: Reaction between benzaldehyde and ethanal will NOT give Cross – Aldol product.

In the light of the above statements, choose the most appropriate answer from the options given below.

[Aldol Condensation Reaction]

  • Statement I is incorrect but Statement II is correct.

     

  • Statement I is correct but Statement II is incorrect.

     

  • Both Statement I and Statement II are correct.

     

  • Both Statement I and Statement II are incorrect.

     

(2)

Aldol condensation is because of acidic character of alpha hydrogen of aldehydes and ketones. Ethanal and benzaldehyde give cross aldol product as follows:

 



Q 3 :    

Two moles of benzaldehyde and one mole of acetone under alkaline conditions using aqueous NaOH after heating gives x as the major product. The number of π bonds in the product x is _______.                [2024]



(9)

 



Q 4 :    

The major product of the following reaction is :             [2025]

CH3CH2CH=Orefluxexcess HСНО alkali?

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  • CH3-CH2-CH2-OH

     

(3)

2 mol of HCHO undergo cross aldol condensation with 1 mol of CH3CH2CHO. The product formed after that undergoes cross Cannizzaro reaction with HCHO.

 

 



Q 5 :    

A man has been asked to synthesise the molecule  (x). He thought of preparing the molecule using an aldol condensation reaction. He found a few cyclic alkenes in his laboratory. He thought of performing ozonolysis reaction on alkene to produce a dicarbonyl compound followed by aldol reaction to prepare “x”. Predict the suitable alkene that can lead to the formation of “x”.            [2025]

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(4)

 



Q 6 :    

Aldol condensation is a popular and classical method to prepare α,β-unsaturated carbonyl compounds. This reaction can be both intermolecular and intramolecular. Predict which one of the following is not a product of intramolecular aldol condensation?            [2025]

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(4)

 



Q 7 :    

When 

undergoes intramolecular aldol condensation, the major product formed is :           [2025]

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(1)

Formation of five membered rings is preferred over formation of seven membered rings in intramolecular aldol condensation.