Q 1 :    

In the Claisen-Schmidt reaction to prepare 351 g of dibenzalacetone using 87 g of acetone, the amount of benzaldehyde required is _______ g. (Nearest integer)                      [2024]



(318)

The condensation of an aromatic aldehyde (without α hydrogen) with an aliphatic aldehyde or ketone (having α hydrogen) in the presence of a strong base (hydroxide or alkoxide) to give α, β unsaturated aldehydes or ketones is called Claisen-Schmidt condensation reaction.

Moles of dibenzalacetone=Mass of dibenzalacetonemolar mass

                                                   =351234mol=1.5mol

By stoichiometry of reaction, moles of benzaldehyde = 2 ×moles of dibenzalacetone = 2 ×1.5 = 3mol.

Mass of benzaldehyde = moles of benzaldehyde ×molar mass of benzaldehyde = 3mol ×106 gmol-1 = 318 g

 



Q 2 :    

The final product A, formed in the following multistep reaction sequence is:                         [2024]

  •  

  •  

  •  

  •  

(2)

 



Q 3 :    

The product of the following reaction is P.                                                 [2024]

The number of hydroxyl groups present in the product P is ______.         



(0)



Q 4 :    

Major product B of the following reaction has ___________ π-bond.                           [2024]



(5)