In the Claisen-Schmidt reaction to prepare 351 g of dibenzalacetone using 87 g of acetone, the amount of benzaldehyde required is _______ g. (Nearest integer) [2024]
(318)
The condensation of an aromatic aldehyde (without hydrogen) with an aliphatic aldehyde or ketone (having hydrogen) in the presence of a strong base (hydroxide or alkoxide) to give , unsaturated aldehydes or ketones is called Claisen-Schmidt condensation reaction.
By stoichiometry of reaction, moles of benzaldehyde = 2 moles of dibenzalacetone = 2 1.5 = 3mol.
Mass of benzaldehyde = moles of benzaldehyde molar mass of benzaldehyde = 3mol 106 = 318 g