Q 1 :    

This reduction reaction is known as:                                   [2024]

  • Rosenmund reduction

     

  • Wolff-Kishner reduction

     

  • Stephen reduction

     

  • Etard reduction

     

(1)

The given reaction is Rosenmund reduction

 



Q 2 :    

In the given reactions, identify the reagent A and reagent B.                         [2024]

  • A-CrO3      B-CrO3

     

  • A-CrO3      B-CrO2Cl2

     

  • A-CrO2Cl2    B-CrO2Cl2

     

  • A-CrO2Cl2    B-CrO3

     

(2)

 



Q 3 :    

Identify the name reaction.                                     [2024]

  • Etard Reaction

     

  • Stephen Reaction

     

  • Gatterman - Koch Reaction

     

  • Rosenmund Reduction

     

(3)

The reaction of benzene or its derivative is treated with carbon monoxide and hydrogen chloride in the presence of anhydrous aluminium chloride or cuprous chloride to form benzaldehyde or substituted benzaldehyde is called the Gatterman-Koch reaction.

 



Q 4 :    

Identify A and B in the following sequence of reaction                                    [2024]

  •  

  •  

  •  

  •  

(2)

On commercial scale benzaldehyde is manufactured by side chain chlorination of toluene followed by hydrolysis.

 



Q 5 :    

In the above chemical reaction sequence "A" and "B" respectively are                             [2024]

 

  • H2O,H+and KMnO4

     

  • O3,Zn/H2O and KMnO4

     

  • H2O,H+ and NaOH(alc)/I2

     

  • O3,Zn/H2O and NaOH(alc)/I2

     

(4)

 



Q 6 :    

The number of the correct reaction(s) among the following is _______.                       [2024]



(1)

Only (C) is correct

 



Q 7 :    

Vanillin compound obtained from vanilla beans, has total sum of oxygen atoms and π electrons is _______.          [2024]



(11)

Sum of oxygen atoms and π electrons = 3 + 8 = 11

 



Q 8 :    

Match List I with List II.              [2025]

[IMAGE 304]

Choose the correct answer from the options given below:

  • A–III, B–IV, C–I, D–II

     

  • A–I, B–III, C–II, D–IV

     

  • A–III, B–IV, C–II, D–I

     

  • A–IV, B–III, C–I, D–II

     

(4)

Fact based

 



Q 9 :    

Which compound would give 3-methyl-6-oxoheptanal upon ozonolysis?          [2025]

  • [IMAGE 305]

     

  • [IMAGE 306]

     

  • [IMAGE 307]

     

  • [IMAGE 308]

     

(2)

[IMAGE 309]

 



Q 10 :    

Given below are two statements:              [2025]

Statement I: Ozonolysis followed by treatment with Zn, H2O of cis-2-butene gives ethanal.

Statement II: The product obtained by ozonolysis followed by treatment with Zn, H2O of 3,6-dimethyloct-4-ene has no chiral carbon atom.

In the light of the above statements, choose the correct answer from the options given below:

  • Both Statement I and Statement II are true.

     

  • Statement I is false but Statement II are true.

     

  • Statement I is true but Statement II is false.

     

  • Both Statement I and Statement II are false.

     

(3)

[IMAGE 310]