Q 1 :    

Major product formed in the following reaction is a mixture of:                           [2024]

  •  

  •  

  •  

  •  

(4)



Q 2 :    

The major product(P) in the following reaction is                             [2024]

  •  

  •  

  •  

  •  

(4)



Q 3 :    

The major products formed:                                            [2024]

A and B respectively are:

  •  

  •  

  •  

  •  

(3)



Q 4 :    

The ratio of number of oxygen atoms to bromine atoms in the product Q is _____ ×10-1.              [2024]



(15)

=nonBr=32=15×10-1



Q 5 :    

Which one of the following reactions will not lead to the desired ether formation in major proportion?

(iso-Bu ⇒ isobutyl, sec-Bu ⇒ sec-butyl, nPr ⇒ n-propyl, tBu ⇒ tert-butyl, Et ⇒ ethyl)            [2025]

  • ButONa+EtBrBu-O-Et

     

  •  

  •  

  • iso-BuONa+sec-BuBrsec-Bu-O-iso-Bu

     

(4)

Williamson ether formation is an SN2 reaction. SN2 reactions give best yield if the attack is on a primary substrate. For secondary substrates, elimination begins to compete with the substitution product, and for tertiary substrates, elimination product is the major product.

 



Q 6 :    

Which one of the following, with HBr will give a phenol?                 [2025]

  •  

  •  

  •  

  •  

(1)