Q 1 :    

Given below are two statements:                              [2025]

In the light of the above statements, choose the most appropriate answer from the options given below:

  • Both Statement I and Statement II are incorrect

     

  • Both Statement I and Statement II are correct

     

  • Statement I is incorrect but Statement II is correct

     

  • Statement I is correct but Statement II is incorrect

     

(2)

In certain substrate molecules with certain type of arrangement of atoms i.e. generally the presence of unshared electron pair at β position to the leaving group, nucleophilic substitutions reactions occur at unexpectedly higher rate along with retention of configuration. This rate enhancement by neighbouring group participation is called anchimeric assistance. N can act as neighbouring group.



Q 2 :    

Match List–I with List–II.                   [2025]

  List–I   List–II
  (Name reaction)   (Product obtainable)
A. Swarts reaction I. Ethyl benzene
B. Sandmeyer’s reaction II. Ethyl iodide
C. Wurtz Fittig reaction III. Cyanobenzene
D. Finkelstein reaction IV. Ethyl fluoride

 

Choose the correct answer from the options given below:

  • A–IV, B–I, C–III, D–II

     

  • A–II, B–III, C–I, D–IV

     

  • A–IV, B–III, C–I, D–II

     

  • A–II, B–I, C–III, D–IV

     

(3)

(A)   C2H5ClAgFC2H5FEthyl fluoride+AgCl

(B) 

(C) 

(D) C2H5Cl+NaI(Finkelstein reaction)AcetoneC2H5I+NaCl

 



Q 3 :    

Match List–I with List–II.           [2025]

  List-I   List–II
  (Reaction)   (Name of Reaction)
A. I. Lucas reaction
B. ArN2+X-HClCuArCl+N2+CuX II. Finkelstein reaction
C. C2H5Br+NaIAcetoneDryC2H5I+NaBr III. Fittig reaction
D. CH3C(OH)(CH3)CH3ZnCl2HClCH3C(Cl)(CH3)CH3 IV. Gattermann reaction

 

Choose the correct answer from the options given below:

  • (A)–(III), (B)–(II), (C)–(IV), (D)–(I)

     

  • (A)–(III), (B)–(IV), (C)–(II), (D)–(I)

     

  • (A)–(IV), (B)–(III), (C)–(I), (D)–(II)

     

  • (A)–(IV), (B)–(I), (C)–(II), (D)–(III)

     

(2)

Fact based

 



Q 4 :    

Predict the major product of the following reaction sequence:            [2025]

  •  

  •  

  •  

  •  

(2)

 



Q 5 :    

Consider the above sequence of reactions. 151 g of 2-bromopentane is made to react. Yield of major product P is 80% whereas Q is 100%.

Mass of product Q obtained is ______ g.

(Given molar mass in g mol-1: H : 1, C : 12, O : 16, Br : 80)  [2025]



(184)

Moles of 2-bromopentane taken initially = Mass of 2-bromopentaneMolar mass of 2-bromopentane
=151151=1 mol

Molar mass of Q (C5H10Br2)

=(5×12+10×1+2×80)g mol-1=230g mol-1

Mass of 0.8 mol Q =0.8×230 g=184 g