Q 1 :

Consider two Group IV metal ions X2+ and Y2+.

A solution containing 0.01 M X2+ and 0.01 M Y2+ is saturated with H2S. The pH at which the metal sulphide YS will form as a precipitate is ________. (Nearest integer)

(Given: Ksp(XS)=1×10-22 at 25°C, Ksp(YS)=4×10-16 at 25°C,

[H2S]=0.1 M in solution,  Ka1×Ka2(H2S)=1.0×10-21, log2=0.30,  log3=0.48,  log5=0.70)                 [2026]

 



(4)

 



Q 2 :

The first and second ionization constants of H2X are 2.5×10-8 and 1.0×10-13 respectively. The concentration of X2- in 0.1H2X solution is______×10-15M. (Nearest Integer)         [2026]



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