Q 1 :

An indicator ‘X’ is used for studying the effect of variation in concentration of iodide on the rate of reaction of iodide ion with H2O2 at room temperature. The indicator ‘X’ forms blue-colored complex with compound ‘A’ present in the solution. The indicator ‘X’ and compound ‘A’ respectively are              [2023]

  • Starch and iodine

     

  • Methyl orange and H2O2

     

  • Methyl orange and iodine

     

  • Starch and H2O2

     

(1)

2Na2S2O3+I2Starch2NaI+Na2S4O6



Q 2 :

Incorrect statement for the use of indicators in acid–base titration is:             [2023]

  • Methyl orange may be used for a weak acid vs weak base titration.

     

  • Phenolphthalein may be used for a strong acid vs strong base titration.

     

  • Methyl orange is a suitable indicator for a strong acid vs weak base titration.

     

  • Phenolphthalein is a suitable indicator for a weak acid vs strong base titration.

     

(1)

Methyl orange is suitable indicator for strong acid vs strong base and strong acid vs weak base titration.

Phenolphthalein is suitable indicator for strong acid vs strong base and weak acid vs strong base titration.

 



Q 3 :

Given below are two statements:

Statement I: In redox titration, the indicators used are sensitive to change in pH of the solution.

Statement II: In acid–base titration, the indicators used are sensitive to change in oxidation potential.

In the light of the above statements, choose the most appropriate answer from the options given below.                 [2023]

  • Statement I is incorrect but Statement II is correct.

     

  • Statement I is correct but Statement II is incorrect.

     

  • Both Statement I and Statement II are incorrect.

     

  • Both Statement I and Statement II are correct.

     

(3)

(I) In redox titration indicators are sensitive to change in oxidation potential.

(II) In acid-base titration, indicators are used which are sensitive to pH.

 



Q 4 :

Given below are two statements:

Statement I: Methyl orange is a weak acid.

Statement II: The benzenoid form of methyl orange is more intense/deeply coloured than the quinonoid form.

In the light of the above statements, choose the most appropriate answer from the options given below:                    [2023]

  • Statement I is incorrect but Statement II is correct

     

  • Both Statement I and Statement II are correct

     

  • Statement I is correct but Statement II is incorrect

     

  • Both Statement I and Statement II are incorrect

     

(4)

Methyl orange is basic in nature

MeOHMe++OH-YellowRed    



Q 5 :

The titration curve of weak acid vs. strong base (with phenolphthalein as indicator) is shown below. The Kphenolphthalein=4×10-10.

Given: log 2=0.3

The number of following statement/s which is/are correct about phenolphthalein is __________.                [2023]

A. It can be used as an indicator for the titration of weak acid with weak base.

B. It begins to change colour at pH = 8.4

C. It is a weak organic base

D. It is colourless in acidic medium              



(2)

1.  Working pH range is 8 to 10

2.  It is colourless in acidic medium and pink in basic medium.

3.  It is an acidic indicator.