Q 1 :    

Given below are two statements:

 

Statement (I) : A Buffer solution is the mixture of a salt and an acid or a base mixed in any particular quantities.

 

Statement (II) : Blood is naturally occurring buffer solution whose pH is maintained by H2CO3/HCO3- concentrations.

 

In the light of the above statements, choose the correct answer from the options given below.               [2024]

  • Both Statement I and Statement II are false

     

  • Statement I is true but Statement II is false

     

  • Statement I is false but Statement II is true

     

  • Both Statement I and Statement lI are true

     

(C)      Acidic buffer: solution of weak acid and its salt with strong base. 

           This buffer is effective in the range 0.1<[acid][salt]<10

           Basic buffer: solution of weak base and its salt with strong acid.

           This buffer is effective in the range 0.1<[base][salt]<10



Q 2 :    

The pH of an aqueous solution containing 1M benzoic acid (pKa=4.20) and 1M sodium benzoate is 4.5. The volume of benzoic acid solution in 300 mL of this buffer solution is ________ mL. (given: log 2 = 0.3)              [2024]



(100)

As total volume of mixture is 300mL, let V mL of 1M benzoic acid is mixed with (300-V) mL of 1M sodium benzoate solution.

Moles of benzoic acid (nacid) = Molarity×volume

                                                = 1M×Vml = Vmmol

Moles of sodium benzoate (nsalt) = Molarity×volume = 1M×(300 - V)mL = (300 - V) mmol

A mixture of benzoic acid (weak acid) and sodium benzoate is an acidic buffer. For acidic buffer:

pH=pKa+log[salt][acid]=pKa+lognsaltnacid

4.5=4.20+log300-VV

log300-VV=0.3

300-VV=2

V=100 mL