Q.

Which of the following contain the same number of atoms

(Given: Molar mass in g mol-1 of H, He, O and S are 1, 4, 16 and 32 respectively)

A. 2 g of O2 gas

B. 4 g of SO2 gas

C. 1400 mL of O2 at STP

D. 0.05 L of He at STP

E. 0.0625 mol of H2 gas

Choose the correct answer from the options given below:               [2026]

1 A and B only  
2 B and C only  
3 C and D only  
4 A, C and E only  

Ans.

(4)

Substance Moles of substance (given mass/molar mass) Number of molecules Atoms = Atomicity × number of molecules
(A) 2 g of O2 gas 232=116 116NA 2×116NA=18NA=0.125NA
(B) 4 g of SO2 gas 464=116 116NA 3×116NA=0.1875NA
(E) H2 gas 0.0625 0.0625NA 2×0.0625NA=0.125NA

 

Volume of gas at STP Moles of substance (Vol in L / 22.4) Number of molecules Atoms = Atomicity × number of molecules
(C) 1400 mL (1.4 L) of O2 gas 1.422.4=116 116NA 2×116NA=18NA=0.125NA
(E) 0.05 L of He gas 0.0522.4=1448 2×116NA=18NA 1448NA=0.00223NA