Q 1 :

Which one of the following compounds can exist as cis-trans isomers?           [2025]

  • 1,1-Dimethylcyclopropane

     

  • 1,2-Dimethylcyclohexane

     

  • Pent-1-ene

     

  • 2-Methylhex-2-ene

     

(2)

1,2-Dimethylcyclohexane will show geometrical isomerism.



Q 2 :

Baeyer’s reagent is                              [2024]

  • acidic potassium permanganate solution

     

  • acidic potassium dichromate solution

     

  • cold, dilute, aqueous solution of potassium permanganate

     

  • hot, concentrated solution of potassium permanganate.

     

(3)

Baeyer's reagent is cold, dilute, aqueous solution of potassium permanganate (KMnO4).

 



Q 3 :

For the given reaction:

'P' is                                           [2024] 

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(2)

Acidic potassium permanganate oxidises alkenes to ketones or acids depending upon the nature of the alkene and the experimental conditions. In the given reaction, major product is carboxylic acid.



Q 4 :

Which amongst the following compounds will show geometrical isomerism?          [2023]

  • Pent-1-ene

     

  • 2,3-Dimethylbut-2-ene

     

  • 2-Methylprop-1-ene

     

  • 3,4-Dimethylhex-3-ene

     

(4)

It shows geometrical isomerism.

 



Q 5 :

Compound X on reaction with O3 followed by Zn/H2O gives formaldehyde and 2-methylpropanal as products. The compound X is      [2022]

  • 3-methylbut-1-ene

     

  • 2-methylbut-1-ene

     

  • 2-methylbut-2-ene

     

  • pent-2-ene

     

(1)

 



Q 6 :

The major product of the following chemical reaction is               [2021]

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(2)

In presence of peroxide, anti-Markownikoff addition reaction takes place.

 



Q 7 :

An alkene on ozonolysis gives methanal as one of the products. Its structure is             [2020]

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(3)

 



Q 8 :

An alkene A on reaction with O3 and Zn–H2O gives propanone and ethanal in equimolar ratio. Addition of HCl to alkene A gives B as the major product. The structure of product B is             [2019]

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(4)

Addition of HCl to an alkene (A) will take place according to Markownikoff’s rule.

 



Q 9 :

The most suitable reagent for the following conversion is                [2019]

  • Hg2+/H+,H2O

     

  • Na/liquid NH3

     

  • H2, Pd/C, quinoline

     

  • Zn/HCl

     

(3)

 



Q 10 :

Which of the following compounds shall not produce propene by reaction with HBr followed by elimination or direct only elimination reaction?        [2016]
 

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  • H3C-H2C-CH2OH

     

  • H2C=C=O

     

  • H3C-CH2-CH2Br

     

(3)

 



Q 11 :

The compound that will react most readily with gaseous bromine has the formula              [2016]
 

  • C3H6

     

  • C2H2

     

  • C4H10

     

  • C2H4

     

(1)

Rate of free radical substitution with Br2(g) depends upon the stability of free radical. Propenyl free radical is allylic free radical which is more stable.

 



Q 12 :

In the reaction with HCl, an alkene reacts in accordance with the Markovnikov’s rule to give a product 1-chloro-1-methyl-cyclohexane. The possible alkene is           [2015]

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  • (A) and (B)

     

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(3)

 



Q 13 :

Which of the following is not the product of dehydration of  ?               [2015]

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(1)