Q 1 :    

Which one of the following compounds can exist as cis-trans isomers?           [2025]

  • 1,1-Dimethylcyclopropane

     

  • 1,2-Dimethylcyclohexane

     

  • Pent-1-ene

     

  • 2-Methylhex-2-ene

     

(2)

1,2-Dimethylcyclohexane will show geometrical isomerism.



Q 2 :    

Baeyer’s reagent is                              [2024]

  • acidic potassium permanganate solution

     

  • acidic potassium dichromate solution

     

  • cold, dilute, aqueous solution of potassium permanganate

     

  • hot, concentrated solution of potassium permanganate.

     

(3)

Baeyer's reagent is cold, dilute, aqueous solution of potassium permanganate (KMnO4).

 



Q 3 :    

For the given reaction:

'P' is                                           [2024] 

  •  

  •  

  •  

  •  

(2)

Acidic potassium permanganate oxidises alkenes to ketones or acids depending upon the nature of the alkene and the experimental conditions. In the given reaction, major product is carboxylic acid.



Q 4 :    

Which amongst the following compounds will show geometrical isomerism?          [2023]

  • Pent-1-ene

     

  • 2,3-Dimethylbut-2-ene

     

  • 2-Methylprop-1-ene

     

  • 3,4-Dimethylhex-3-ene

     

(4)

It shows geometrical isomerism.

 



Q 5 :    

Compound X on reaction with O3 followed by Zn/H2O gives formaldehyde and 2-methylpropanal as products. The compound X is      [2022]

  • 3-methylbut-1-ene

     

  • 2-methylbut-1-ene

     

  • 2-methylbut-2-ene

     

  • pent-2-ene

     

(1)

 



Q 6 :    

The major product of the following chemical reaction is               [2021]

  •  

  •  

  •  

  •  

(2)

In presence of peroxide, anti-Markownikoff addition reaction takes place.

 



Q 7 :    

An alkene on ozonolysis gives methanal as one of the products. Its structure is             [2020]

  •  

  •  

  •  

  •  

(3)

 



Q 8 :    

An alkene A on reaction with O3 and Zn–H2O gives propanone and ethanal in equimolar ratio. Addition of HCl to alkene A gives B as the major product. The structure of product B is             [2019]

  •  

  •  

  •  

  •  

(4)

Addition of HCl to an alkene (A) will take place according to Markownikoff’s rule.

 



Q 9 :    

The most suitable reagent for the following conversion is                [2019]

  • Hg2+/H+,H2O

     

  • Na/liquid NH3

     

  • H2, Pd/C, quinoline

     

  • Zn/HCl

     

(3)

 



Q 10 :    

Which of the following compounds shall not produce propene by reaction with HBr followed by elimination or direct only elimination reaction?        [2016]
 

  •  

  • H3C-H2C-CH2OH

     

  • H2C=C=O

     

  • H3C-CH2-CH2Br

     

(3)