Q.

When 1 g of compound (X) is subjected to Kjeldahl's method for estimation of nitrogen, 15 mL 1 M H2SO4 was neutralized by ammonia evolved. The percentage of nitrogen in compound (X) is :        [2026]

1 0.42  
2 42  
3 0.21  
4 21  

Ans.

(2)

eq. of H2SO4=eq. of Ammonia

15×1×21000=moles of ammonia×1

Moles of ammonia=moles of 'N'

Weight of nitrogen=15×1×21000×14=0.42

% weight of 'N'=0.421×100=42%