Q.

An oxide of iron contains 69.9% iron, its empirical formula, is:

(Given: Molar mass of Fe and O are 56 and 16 g mol-1 respectively.)             [2026]

1 FeO  
2 Fe2O3  
3 Fe3O4  
4 FeO3  

Ans.

(2)

Element Mass percentage (%w/w) Number of gram atoms per 100 g compound = (%w/w)/gram atomic mass Relative ratio Simple ratio
Fe 69.9 69.956=1.25 1.251.25=1 2
O 100 − 69.9 = 30.1 1.88 1.881.25=1.5 3

 

Empirical formula = Fe2O3