Q.

Complete combustion of X g of an organic compound gave 0.25 g of CO2 and 0.12 g of H2O. If the % of carbon is 25% and of hydrogen is 4.89%, then X = _____ ×10-3 g. (Nearest integer)

(Molar mass of C, H and O are 12, 1 and 16 g mol-1 respectively.)              [2026]

1 273  
2 27  
3 2730  
4 227  

Ans.

(1)

Moles of CO2=Given massMolar mass=(0.2544) mol

Moles of C in X g organic compound

=Moles of CO2=(0.2544) mol

Mass of C in organic compound

=moles of C×molar mass of C=0.2544×12 g

Mass percentage of C in organic compound

=0.25×1244X×100=25,  X=0.2727≈273×10-3 g