Q.

14.0 g of calcium metal is allowed to react with excess HCl at 1.0 atm pressure and 273 K. Which of the following statements is incorrect  

[Given : Molar mass in g mol of Ca –40-1, Cl –35.5, H – 1]               [2026]

1 7.84 L of  H2 gas is evolved.  
2 0.35 mol of H2 gas is evolved.  
3 The limiting reagent is calcium metal.  
4 33.3 g of CaCl2 is produced.  

Ans.

(4)

Ca(s)+2HCl(g)CaCl2(s)+H2(g)1440excess--

= 0.35 mole                      0.35 mole        0.35 mole

Volume of H2(g) evolved=0.35×22.4=7.84 L

(4) is wrong because weight of CaCl2=0.35×111=38.85 g