Q 21 :

Which is not true for arginine?           [2023]

  • It has a fairly high melting point.

     

  • It has high solubility in benzene.

     

  • It is associated with more than one pKa values.

     

  • It is a crystalline solid.

     

(2)

Arginine exist as zwitter ion and such ionic compounds are insoluble in non polar solvent like “benzene”.

 



Q 22 :

Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R.

Assertion A: A solution of the product obtained by heating a mole of glycine with a mole of chlorine in presence of red phosphorous generates chiral carbon atom.

Reason R: A molecule with 2 chiral carbons is always optically active.

In the light of the above statements, choose the correct answer from the options given below:               [2023]

  • Both A and R are true but R is NOT the correct explanation of A.

     

  • A is true but R is false

     

  • A is false but R is true

     

  • Both A and R are true and R is the correct explanation of A.

     

(2)

Optical activity does not depend on chiral carbon. Meso compounds are optically inactive.



Q 23 :

Total number of tripeptides possible by mixing of valine and proline is ________.      [2023]



(8)

Pro-Val-Pro
Pro-Val-Val
Val-Pro-Pro
Val-Pro-Val
Val-Val-Pro
Pro-Pro-Val
Val-Val-Val
Pro-Pro-Pro



Q 24 :

A short peptide on complete hydrolysis produces 3 moles of glycine (G), two moles of leucine (L) and two moles of valine (V) per mole of peptide. The number of peptide linkages in it are ________.              [2023]



(6)

Three moles of glycine (G), two moles of leucine (L) and two moles of valine (V) per mole of peptide show that peptide chain has 7 amino acids, that is a heptapeptide chain. The number of peptide linkages in it are 6.



Q 25 :

In an oligopeptide named alanylglycylphenyl alanylisoleucine, the number of sp2 hybridised carbons is ________.    [2023]



(10)