Which one is not correct mathematical equation for Dalton’s Law of partial pressure? Here p = total pressure of gaseous mixture

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Solution

Q.
Which one is not correct mathematical equation for Dalton’s Law of partial pressure Here p = total pressure of gaseous mixture [2022]

1 $p_{i} = x_{i} p_{i}^{0}$ , where $x_{i}$ = mole fraction of $i^{t h}$ gas in gaseous mixture
$p_{i}^{0}$ = pressure of $i^{t h}$ gas in pure state

2 $p = p_{1} + p_{2} + p_{3}$

3 $p = \frac{n_{1} R T}{V} + \frac{n_{2} R T}{V} + \frac{n_{3} R T}{V}$

4 $p_{i} = x_{i} p$ , where $p_{i}$ = partial pressure of $i^{t h}$ gas
$x_{i}$ = mole fraction of $i^{t h}$ gas in gaseous mixture

Ans.
(1)

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