Which of the following complex is homoleptic?

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Q.
Which of the following complex is homoleptic [2024]

1 ${[Ni {(CN)}_{4}]}^{2 -}$

2 $[{Ni(NH}_{3})_{2} {Cl}_{2}]$

3 ${[{Fe(NH}_{3})_{4} {Cl}_{2}]}^{+}$

4 ${[{Co(NH}_{3})_{4} {Cl}_{2}]}^{+}$

Ans.
(1)

Complexes in which a metal is bound to only one kind of donor groups are known as homoleptic. Complexes in which a metal is bound to more than one kind of donor groups are known as heteroleptic. (1) is homoleptic. (2), (3) and (4) are heteroleptic.

Solution

Q.
Which of the following complex is homoleptic [2024]

1 ${[Ni {(CN)}_{4}]}^{2 -}$

2 $[{Ni(NH}_{3})_{2} {Cl}_{2}]$

3 ${[{Fe(NH}_{3})_{4} {Cl}_{2}]}^{+}$

4 ${[{Co(NH}_{3})_{4} {Cl}_{2}]}^{+}$

Ans.
(1)

Complexes in which a metal is bound to only one kind of donor groups are known as homoleptic. Complexes in which a metal is bound to more than one kind of donor groups are known as heteroleptic. (1) is homoleptic. (2), (3) and (4) are heteroleptic.

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Solution

Q. Which of the following complex is homoleptic [2024]

1 [Ni(CN)4]2-

2 [Ni(NH3)2Cl2]

3 [Fe(NH3)4Cl2]+

4 [Co(NH3)4Cl2]+

Ans. (1) Complexes in which a metal is bound to only one kind of donor groups are known as homoleptic. Complexes in which a metal is bound to more than one kind of donor groups are known as heteroleptic. (1) is homoleptic. (2), (3) and (4) are heteroleptic.

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Q.
Which of the following complex is homoleptic [2024]

1 ${[Ni {(CN)}_{4}]}^{2 -}$

2 $[{Ni(NH}_{3})_{2} {Cl}_{2}]$

3 ${[{Fe(NH}_{3})_{4} {Cl}_{2}]}^{+}$

4 ${[{Co(NH}_{3})_{4} {Cl}_{2}]}^{+}$

Ans.
(1)

Complexes in which a metal is bound to only one kind of donor groups are known as homoleptic. Complexes in which a metal is bound to more than one kind of donor groups are known as heteroleptic. (1) is homoleptic. (2), (3) and (4) are heteroleptic.