Q.

Which of the following salts do not contain water of crystallisation

1 Blue vitriol  
2 Baking soda  
3 Washing soda  
4 Gypsum  

Ans.

(2)

Baking soda is sodium bicarbonate (NaHCO3) in anhydrous form without any water of crystallisation.
Other options: 
Blue Vitriol: It is hydrated salt of copper sulphate containing 5 molecules of water of crystallisation (CuSO4·5H2O).
Washing soda: It is hydrated salt of sodium carbonate containing 10 molecules of water of crystallisation (Na2CO3·10H2O).
Gypsum: It is hydrated salt of calcium sulphate containing 2 molecules of water of crystallisation (CaSO4·2H2O).