Q.

What is the energy (in J atom-1) required for the following process

Li2+(g)⟶Li3+(g)+e-

(Take the ionisation energy for the H atom in the ground state as 2.18×10-18 J atom-1)                  [2026]

1 8.72×10-18  
2 1.962×10-18  
3 1.962×10-17  
4 6.54×10-17  

Ans.

(3)

ELi2+/Li3+=EH/H+×Z2

ELi2+/Li3+=2.18×10-18×32 J atom-1

ELi2+/Li3+=1.962×10-17 J atom-1