Q.

Two soap bubbles A and B are kept in a closed chamber where the air is maintained at pressure 8 N/m2. The radii of bubbles A and B are 2 cm and 4 cm, respectively. Surface tension of the soap-water used to make bubbles is 0.04 N/m. Find the ratio nBnA, where nA and nB are the number of moles of air in bubbles A and B, respectively.  [Neglect the effect of gravity.]                   [2009]


Ans.

(6)

 Pressure,

PA=Pair+4TRA

( Excess pressure due to surface tension (T) in soap bubble =4Tr)

PA=8+4TRA=4×0.040.02+8PA=16 N/m2

Similarly, PB=8+4TRB=8+4×0.040.04=12 N/m2

According to ideal gas equation, PV=nRT

PAVA=nARTB16×43π(0.02)3=nARTA         ...(i)

PBVB=nBRTB12×43π(0.04)3=nBRTB       ...(ii)

Dividing eq. (ii) by (i)

12×43π(0.04)316×43π(0.02)3=nBnA             [TA=TB]

  nBnA=6