Q.

Total number of unpaired electrons present in the central metal atoms/ions of

[Ni(CO)4], [NiCl4]2-, [PtCl2(NH3)2], [Ni(CN)4]2- and [Pt(CN)4]2- is_______.   [2026]


Ans.

(2)

In [Ni(CO)4], Ni0:3d84s2

Hybridisation state : sp3

Unpaired electron = 0

In [NiCl4]2-, Ni2+:3d8

Hybridisation state : sp3

Unpaired electron = 2

In [PtCl4]2-, Pt2+:5d8

Hybridisation state : dsp2

Unpaired electron = 0

In [Ni(CN)4]2-, Ni2+:3d8

Hybridisation state : dsp2

Unpaired electron = 0

In [Pt(NH3)2Cl2], Pt2+:5d8

Hybridisation state : dsp2

Unpaired electron = 0