Q.

In a mixture of H–He+ gas (He+ is a singly ionized He atom), H atoms and He+ ions are excited to their respective first excited states. Subsequently, H atoms transfer their total excitation energy to He+ ions (by collisions). Assume that the Bohr model of the atom is exactly valid.              [2008]

 

Q.   The wavelength of light emitted in the visible region by He+ ions after collisions with H atoms is

1 6.5×10-7 m  
2 5.6×10-7 m  
3 4.8×10-7 m  
4 4.0×10-7 m  

Ans.

(3)

Wavelength of visible light lies in the range,

λ1=4000 Å to λ2=7000 Å

Therefore,    E1=12375λ1=123754000=3.09 eV

                     E2=12375λ2=123757000=1.77 eV

For He+ atom, in the transition from n=4 to n=3, the energy of the photon released will lie between E1 and E2.

E4-E3=-3.4-(-6.04)=2.64 eV

∴ Wavelength of the photon corresponding to this energy (2.64 eV),

λ=123752.64Å=4687.5Å=4.68×10-7 m