Q.

When a particle is restricted to move along the x-axis between x=0 and x=a, where a is of nanometer dimension, its energy can take only certain specific values. The allowed energies of the particle moving in such a restricted region, correspond to the formation of standing waves with nodes at its ends x=0 and x=a. The wavelength of this standing wave is related to the linear momentum p of the particle according to the de Broglie relation. The energy of the particle of mass m is related to its linear momentum as E=p22m. Thus, the energy of the particle can be denoted by a quantum number 'n' taking values 1,2,3,… (n=1, called the ground state) corresponding to the number of loops in the standing wave.

Use the model described above to answer the following three questions for a particle moving in the line x=0 to x=a. Take h=6.6×10-34J s and e=1.6×10-19C.                  

Q.     The speed of the particle, that can take discrete values, is proportional to                  [2009]

1 n-3/2  
2 n-1  
3 n1/2  
4 n  

Ans.

(4)

λ=hp⇒λ=hmv

But,  nλ2=a⇒λ=2an

∴  hmv=2an

∴  mv=nh2a⇒v=nh2am

∴  v∝n