Q.

The specific conductance of a saturated solution of silver bromide is k Scm-1. The limiting ionic conductivity of Ag+ and Br- ions are x and y, respectively. The solubility of silver bromide in gL-1 is:

(molar mass of AgBr = 188)

1 k×1000x-y  
2 kx+y×188  
3 k×1000×188x+y  
4 x+yk×1000188  

Ans.

(3)

Λm=kM×1000·(x+y)=kM×1000

                          M=1000×kx+y

Solubility (in g L-1)=k×1000×188x+y