The species which does not undergo disproportionation reaction is : [2025]

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Solution

Q.
The species which does not undergo disproportionation reaction is : [2025]

1 ${ClO}_{2}^{-}$

2 ${ClO}_{3}^{-}$

3 ${ClO}^{-}$

4 ${ClO}_{4}^{-}$

Ans.
(4)

$\overset{+ 1}{Cl} O^{-}, \overset{+ 3}{Cl} O_{2}^{-}, \overset{+ 5}{Cl} O_{3}^{-}, \overset{+ 7}{Cl} O_{4}^{-}$

$Cl$ cannot be oxidized beyond +7 oxidation state, so $\overset{+ 7}{Cl} O_{4}^{-}$ cannot undergo disproportionation.

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