Read the passage carefully and answer the following questions from (i) to (v):
Balanced chemical equation has an equal number of atoms of different elements in the reactants and products. According to law of conservation of mass, matter can neither be created nor be destroyed in a chemical reaction.
(ii) The following represent the exothermic reaction. The reactants react to form product, with the release of energy in the form of heat

Which of the following involve an exothermic reaction
(4)