Q.

The equation for real gas is given by (P+aV2)(V–b)=RT, where P, V, T and R are the pressure, volume, temperature and gas constant, respectively. The dimension of ab–2 is equivalent to that of :          [2025]

1 Planck's constant  
2 Compressibility  
3 Strain  
4 Energy density  

Ans.

(4)

Given, [P+aV2](V–b)=RT

[P]=[aV2] ⇒ [a]=[P][V2]

[a]=[P][V2]=[ML–1T–2][L6]=ML5T–2

[b]=[V]=L3

[ab–2]=[ML5T–2L–6]=[ML–1T–2]

Dimension of energy density.