Q.

The electron in a hydrogen atom makes a transition from an excited state to the ground state. Which of the following statements is true                [2000]

1 Its kinetic energy increases and its potential and total energies decrease.  
2 Its kinetic energy decreases, potential energy increases and its total energy remains the same.  
3 Its kinetic and total energies decrease and its potential energy increases.  
4 Its kinetic, potential and total energies decrease.  

Ans.

(1)

According to the question, in a hydrogen atom, the electron makes a transition from an excited state to the ground state, i.e., the electron comes closer to the nucleus, so r decreases.

∴ Potential Energy (P.E.)=-KZe2r

∴ Potential energy decreases.

Kinetic energy (K.E.) will increase.

∵  K.E.=12KZe2r

∴  Total energy decreases.

∵  T.E.=P.E.+K.E.=-12KZe2r