Q.

The electric potential between a proton and an electron is given by V=V0ln(rr0), where r0 is a constant. Assuming Bohr's model to be applicable, write variation of rn with n, n being the principal quantum number                     [2003]

1 rn∝n  
2 rn∝1n  
3 rn∝n2  
4 rn∝1n2  

Ans.

(1)

Given potential energy (U) between electron and proton

U=eV0ln(rr0)      [∵ |U|=eV]

∴  |F|=|-dUdr|=ddr[eV0ln(rr0)]=eV0r0×1r

This force will provide the necessary centripetal force.

∴  mv2r=eV0rr0 ⇒ mv2=eV0r0         ⋯(i)

As per Bohr's postulate, mvr=nh2π         ⋯(ii)

From Eqs. (i) and (ii),

m2v2r2mv2=n2h2r04π2V0e⇒  r2=n2h2r04π2V0me

∴  r∝n