Q.

When a particle is restricted to move along the x-axis between x=0 and x=a, where a is of nanometer dimension, its energy can take only certain specific values. The allowed energies of the particle moving in such a restricted region, correspond to the formation of standing waves with nodes at its ends x=0 and x=a. The wavelength of this standing wave is related to the linear momentum p of the particle according to the de Broglie relation. The energy of the particle of mass m is related to its linear momentum as E=p22m. Thus, the energy of the particle can be denoted by a quantum number 'n' taking values 1,2,3,… (n=1, called the ground state) corresponding to the number of loops in the standing wave.

Use the model described above to answer the following three questions for a particle moving in the line x=0 to x=a. Take h=6.6×10-34J s and e=1.6×10-19C.

Q.    The allowed energy for the particle for a particular value of n is proportional to                  [2009]

1 a-2  
2 a-3/2  
3 a-1  
4 a2  

Ans.

(1)

Energy,  E=h22mλ2           (∵ E=P22m and P=hλ)

The length in which the particle is restricted to move is 

a=nλ2⇒λ=2an

Putting this value of λ, we get

E=h2n22m×4a2=n2h28ma2

∴  E∝a-2