Q.

Given below are two statements :

Statement I: The number of pairs among [SiO2, CO2], [SnO, SnO2], [PbO, PbO2] and [GeO, GeO2] which contain oxides that are both amphoteric is 2.

Statement II: BF3 is an electron deficient molecule, can act as a Lewis acid, forms adduct with NH3 and has a trigonal planar geometry.

In the light of the above statements, choose the correct answer from the options given below             [2026]

1 Statement I is false but Statement II is true  
2 Both Statement I and Statement II are false  
3 Statement I is true but Statement II is false  
4 Both Statement I and Statement II are true  

Ans.

(4)

⇒SiO2, CO2, GeO, GeO2 are acidic in nature.

SnO, SnO2, PbO, PbO2 are amphoteric in nature.

⇒BF3 is Lewis acid according to Lewis octet theory and has sp2 hybridization with trigonal planar geometry and it can accept lone pair from ammonia to form adduct.