Q.

Given below are two statements :

Statement I: The number of pairs among [SiO2,CO2], [SnO,SnO2], [PbO,PbO2] and [GeO,GeO2] which contain oxides that are both amphoteric is 2.

Statement II: BF3 is an electron deficient molecule, can act as a Lewis acid, forms adduct with NH3 and has a trigonal planar geometry.

In the light of the above statements, choose the correct answer from the options given below             [2026]

1 Statement I is false but Statement II is true  
2 Both Statement I and Statement II are false  
3 Statement I is true but Statement II is false  
4 Both Statement I and Statement II are true  

Ans.

(4)

SiO2, CO2, GeO, GeO2 are acidic in nature.

SnO, SnO2, PbO, PbO2 are amphoteric in nature.

BF3 is Lewis acid according to Lewis octet theory and has sp2 hybridization with trigonal planar geometry and it can accept lone pair from ammonia to form adduct.