Q.

One mole of diatomic gas having rotational modes only is kept in a cylinder with a piston system. The cross-section area of the cylinder is 4 cm2. The gas is heated slowly to raise the temperature by 1.2°C during which the piston moves by 25 mm. The amount of heat supplied to the gas is ______ J. (Atmospheric pressure = 100 kPa, R = 8.3 J/mol·K) (Neglect mass of the piston)                 [2026]

1 24.8  
2 25  
3 15.04  
4 29.98  

Ans.

(2)

Q=ΔU+W

Q=f2nRΔT+PΔV

Diatomic gas f=5

Q=52×1×8.3×1.2+100×103(4×10-4×0.025)

Q=24.9+1=25.9 J, nearest answer is 25

Here, please note that instead of the above method, if we use Q=nCpΔT, then also no option matches.