Q.

One mole of a monatomic ideal gas goes through a thermodynamic cycle, as shown in the volume versus temperature (V-T) diagram. The correct statement(s) is/are:     [R is the gas constant]                            [2019]

1 Work done in this thermodynamic cycle (1→2→3→4→1) is |W|=12RT0  
2 The above thermodynamic cycle exhibits only isochoric and adiabatic processes.  
3 The ratio of heat transfer during processes 1→2 and 2→3 is |Q1→2Q2→3|=53  
4 The ratio of heat transfer during processes 1→2 and 3→4 is |Q1→2Q3→4|=12  

Ans.

(1, 3)

The P-V graph of the given V-T graph is given below.

(1)  Work done during cyclic process (1→2→3→4→1)

W=area enclosed in the loop=P02V0

∵ P0V0=nRT0               ∴ P0V02=nRT02

∴  Work done W=nRT01=RT02    [as n=1]

(2)  Process 1→2 is isobaric

Process 2→3 is isochoric

Process 3→4 is isobaric

Process 4→1 is isochoric

Hence no adiabatic process is involved.

(3)  |ΔQ1→2|=|nCpΔT|=|nCp(2T0-T0)|=|nCpT0|

|ΔQ2→3|=|ΔU|=|nCvΔT|=|nCvT0|

∴ |ΔQ1→2ΔQ2→3|=CpCv=53

(4)  |ΔQ3→4|=nCpT02

∴ |ΔQ1→2ΔQ3→4|=nCpT0nCpT02=21