Maximum bond angle at nitrogen is present in which of the following? [2015]

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Solution

Q.
Maximum bond angle at nitrogen is present in which of the following [2015]

1 ${NO}_{2}^{+}$

2 ${NO}_{3}^{-}$

3 ${NO}_{2}$

4 ${NO}_{2}^{-}$

Ans.
(1)

Species ${NO}_{3}^{-}$ ${NO}_{2}$ ${NO}_{2}^{-}$ ${NO}_{2}^{+}$

Hybridisation $s p^{2}$ $s p^{2}$ $s p^{2}$ $sp$

Bond angle $120 °$ $134 °$ $115 °$ $180 °$

So, ${NO}_{2}^{+}$ has maximum bond angle.

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