Q.

Match List-I with List-II.                    [2024]

  List-I
(Solid salt treated with dil. H2SO4)
  List-II
(Anion detected)
   
A. Effervescence of colourless gas I. NO2-
B. Gas with smell of rotten egg II. CO32-
C. Gas with pungent smell III. S2-
D. Brown fumes IV. SO32-

 

Choose the correct answer from the options given below:

1 A – II, B – III, C – IV, D – I  
2 A – IV, B – III, C – II, D – I  
3 A – I, B – II, C – III, D – IV  
4 A – II, B – III, C – I, D – IV  

Ans.

(1)

Experiment Observation Anion detected
Solid salt + dil. H2SO4 A. Effervescence of colourless and odourless gas which turns lime water milky. (II) CO32- is confirmed.
B. Colourless gas with rotten egg smell and turns lead acetate paper black. (III) S2- is confirmed.
C. Colourless gas with pungent smell. Heat and pass the gas through acidified K2Cr2O7 solution. (IV) SO32- is confirmed.
D. Colourless gas followed by brown gas (Brown fumes) and it turns ferrous sulphate solution black. (I) NO2- is confirmed.