Q.

Match List I with List II.         [2025]

  List I   List II
  (Transition metal ion)   (Spin only magnetic moment (B.M.))
A. Ti3+ I. 3.87
B. V2+ II. 0.00
C. Ni2+ III. 1.73
D. Sc3+ IV. 2.84

 

Choose the correct answer from the options given below:

1 A–III, B–I, C–IV, D–II  
2 A–III, B–I, C–II, D–IV  
3 A–IV, B–II, C–III, D–I  
4 A–II, B–IV, C–I, D–III  

Ans.

(1)

Transition metal ion Electronic configuration Number of unpaired electrons (n) Spin only magnetic moment (μ)=n(n+2)BM
Ti3+ [Ar]183d1 1 1(1+2)BM=1.73 BM
V2+ [Ar]183d3 3 3(3+2)BM=3.87 BM
Ni2+ [Ar]183d8 2 2(2+2)BM=2.83 BM 
Sc3+ [Ar]183d0 0 0(0+2)BM=0 BM