Q.

In Carius method, 0.75 g of an organic compound gave 1.2 g of barium sulphate, find percentage of sulphur (molar mass 32 g mol⁻¹). Molar mass of barium sulphate is 233 g mol⁻¹.              [2026]

1 4.55%  
2 21.97%  
3 16.48%  
4 10.30%  

Ans.

(2)

nBaSO4×32W(unknown comp.)×100

=1.2×32233×1000.75=21.97%