Q.

In a radioactive sample, K1940 nuclei either decay into stable Ca2040 nuclei with decay constant 4.5×10-10 per year or into stable Ar1840 nuclei with decay constant 0.5×10-10 per year. Given that in this sample all the stable Ca2040 and Ar1840 nuclei are produced by the K1940 nuclei only. In time t×109 years, if the ratio of the sum of stable Ca2040 and Ar1840 nuclei to the radioactive K1940 nuclei is 99, the value of t will be         [Given: ln 10 = 2.3]                   [2019]

1 9.2  
2 4.6  
3 1.15  
4 2.3  

Ans.

(1)

Here -dNdt=λ1N+λ2N

In integrating on both sides,

t=2.303λ1+λ2log10(N0N)⇒t=2.3035×10-10log10(1001)

                                                                      [∵ λ1+λ2=4.5×10-10+0.5×10-10 and N0N=100]

∴ t=9.2×109 year