Q.

In a fuel cell methanol is used as fuel and oxygen gas is used as an oxidizer. The reaction is CH3OH(l)+32O2(g)→CO2(g)+2H2O(l)

At 298 K standard Gibb's energies of formation for CH3OH(l), H2O(l) and CO2(g) are -166.2,-237.2 and -394.4 kJ mol-1 respectively. If standard enthalpy of combustion of methanol is -726 kJ mol-1, find the efficiency (in %) of the fuel cell:


Ans.

(97)

ΔG=ΔGp-ΔGr