Q.

For the given reaction;

CaCO3+2HClCaCl2+H2O+CO2

If 90 g CaCO3 is added to 300 mL of HCl which contains 38.55% HCl by mass and has density 1.13 g mL-1, then which of the following option is correct  

Given molar mass of H, Cl, Ca and O are 1, 35.5, 40 and 16 g mol-1 respectively.  [2026]

1 97.30 g of HCl reacted  
2 64.97 g of HCl remains unreacted  
3 60.32 g of HCl remains unreacted  
4 32.85 g of CaCO3 remains unreacted  

Ans.

(2)

Density of HCl solution (d)=1.13 g/mL

V=300 mL

Wt. of HCl solution=339 g

Wt. of HCl=339×38.55100=130.68 g

(LR)CaCO3+2HClCaCl2+H2O+CO290100130.6836.5=0.90 mole=3.58 mole

Moles of HCl remained=1.78 mole 

Mass of HCl remained=64.97 g