Q.

Hydrogen gas absorbs radiations of wavelength λ0 and consequently emit radiations of 6 different wavelengths of which three wavelengths are shorter than λ0. Choose the CORRECT statement(s).

1 The final energy state of the atom is n=4  
2 The initial state of the atom may be n=2  
3 There are two transitions in Balmer series  
4 There are three transitions belonging to Lyman series  

Ans.

(1,2,3,4)

Since only 6 different wavelengths are excited, therefore highest excited state is n=4.

Two wavelengths are shorter than λ0. Initially atoms were in excited state n=2.

Corresponding transitions are 4 → 3, 4 → 2, 4 → 1, 3 → 2, 3 → 1, 2 → 1.