Q.

Given below are two statements:

Statement I: The number of species among BF4-, SiF4, XeF4 and SF4, that have unequal E−F bond lengths is two. Here, E is the central atom.

Statement II: Among O2-, O22-, F2 and O2+, O2- has the highest bond order.

In the light of the above statements, choose the correct answer from the options given below:   [2026]

1 Statement I is false but Statement II is true  
2 Both Statement I and Statement II are true  
3 Statement I is true but Statement II is false  
4 Both Statement I and Statement II are false  

Ans.

(4)

In BF4-, SiF4 and  XeF4 all bond lengths are identical

Molecules           B.O.

O2+          →     2.5

O2-          →     1.5

O22-        →      1

F2           →       1