Q.

Given below are two statements :

Statement I : The correct order in terms of bond dissociation enthalpy is Cl2>Br2>F2>I2.

Statement II : The correct trend in the covalent character of the metal halides is [SnCl4>SnCl2], [PbCl4>PbCl2] and [UF4>UF6].

In the light of the above statements, choose the correct answer from the options given below :     [2026]

1 Both Statement I and Statement II are true  
2 Statement I is true but Statement II is false  
3 Both Statement I and Statement II are false  
4 Statement I is false but Statement II is true  

Ans.

(2)

Statement-I :

Bond energy order is Cl2>Br2>F2>I2

Bond energy increases with increase in bond order.

Statement-II :

Correct order of covalent character

According to Fajan's rule, higher the charge on cation, greater is the covalent character.

PbCl2<PbCl4,

UF6>UF4,

SnCl4>SnCl2