Q.

Given below are two statements :

Statement I : The correct order in terms of atomic/ionic radii is Al>Mg>Mg2+>Al3+.

Statement II : The correct order in terms of the magnitude of electron gain enthalpy is Cl>Br>S>O

In the light of the above statements, choose the correct answer from the options given below :      [2026]

1 Both Statement I and Statement II are true  
2 Statement I is true but Statement II is false  
3 Statement I is false but Statement II is true  
4 Both Statement I and Statement II are false  

Ans.

(3)

Correct order of size is Mg>Al>Mg2+>Al3+

Atomic size depends mainly upon Zeffective and shell number.

Generally on moving down the group electron affinity decreases 

and on moving across the period electron affinity increases.

In the periodic table Cl has maximum electron affinity.

Halogen has higher electron affinity than Chalcogen.

Cl>Br>S>O