Q.

Consider the expansion of one mole of an ideal gas from an initial state to a final state, with ΔS representing the entropy change in the process. The correct statement is:

1 If the process is carried out reversibly, the value of ΔS will be higher in comparison to its irreversible counterpart.  
2 If the process is adiabatic, the value of ΔS is always zero, irrespective of whether the process is carried out reversibly or irreversibly.  
3 If the process is isothermal, there will not be any heat exchange with the surrounding since the temperatures of the system and the surrounding are equal.  
4 If the process is isothermal and the final volume is double of the initial volume, the value of ΔS will be independent of the temperature.  

Ans.

(4)

For isothermal, ΔSsys=nRln(VfVi)