Q.

Consider one mole of helium gas enclosed in a container at initial pressure P1 and volume V1. It expands isothermally to volume 4V1. After this, the gas expands adiabatically and its volume becomes 32V1. The work done by the gas during isothermal and adiabatic expansion processes are Wiso and Wadia, respectively. If the ratio WisoWadia=fln2, then f is _______.                           [2020]


Ans.

(1.78)

For monoatomic gas, γ=53

In adiabatic process P1V1γ=P2V2γ

⇒P14(4V1)5/3=P2(32V1)5/3

⇒P2=P14(18)5/3=P1128

And Wadi=P1V1-P2V2γ-1=P1V1-P1128(32V1)53-1

=P1V1(34)23=98P1V1

In isothermal process,

Wiso=2.303 μRTlog10(V2V1)

⇒Wiso=P1V1ln(4V1V1)=2P1V1ln2

∴  WisoWadia=2P1V1ln298P1V1=169ln2=fln2

So, f=169=1.7778≈1.78